The VMware Version is an Image for VMware and not made for booting from it , it is not a full functionally Operation System.
I suppose you have no OS on you second hdd, so this error is preassigned.after going through the BIOS to boot of the secondary HD i receive the message:
NTLDR is missing
If you need more info , read ntldrismissing.com.
Download the usb version or the live cd and follow one of the numerous tutorials how to install BT to hd, or use your VMware Image within VMware!