Damn Vulnerable Linux has some vulnerable services on it that you can start up and configure to listen on the network.
There's also a good list of deliberately insecure web apps here, which was posted onto the forums a while ago, in a thread dedicated to learning resources (I think). Don't have a link to that thread handy, but here's the insecure web app link:
http://www.irongeek.com/i.php?page=s...b-app-security



